[o-info] Q&A connectivity ...

From: Alwyn Jones (alwyn@xray.bmc.uu.se)
Date: Wed Feb 14 2007 - 02:01:18 CST


 >I am having some trouble with a peptide ligand bound
to my protein.  It is an 8-residue ligand and one of
the residues is post-translationally modified.
Because of this, when I load the model into O none of
the residues in the ligand are connected (i.e. no
peptide bonds).  I am wondering how I can tell O to
connect all the residues?  If I do 'make bond' between
them all it is fine at first, but after a round of
refinement the bonds are lost again when I load the
new model.


the stereo_chem.odb entry contains the residue connectivity used by O  
to generate the 'bonds' you see on the screen. if your molecule does  
not have a descriptor in this entry, O tries to connect within just  
the residue using a set of distance criteria. so you have a few choices:
1/ do nothing. the 'bonds' on the screen don't mean a lot about your  
stereochemistry so you do NOT have to have them all. O uses the  
screen connectivity for some commands (eg. tor_gen, graqb_group)  
otherwise they are cosmetic.
2/ make a new entry in the stereo_chem.odb for you residue. this is  
'easy'. the entry does not have to be full, i.e. describing all the  
stereochemistry etc, just the connect records and usually just the  
'connect_all' records are sufficient. if you want to rebuild the  
residue, you might want to add a few more things. remember to change  
the line count at the header record for the ODB entry. drop me a line  
if you need help
3/ make a little macro to draw each extra bond that you'll need to  
activate every time you read in new coords. something like this for  
each bond:

bond_make
term_id m1 a5 O obj
term_id m1 a6 N obj
....

happy valentine's day

Alwyn Jones
alwyn@xray.bmc.uu.se
http://xray.bmc.uu.se/alwyn



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